Archives de catégorie : WOMS Story

The OpenFluor database

For those who are interested in PARAFAC, below is the update I promised on the new tools discussed in my presentation.

(1)  The drEEM toolbox, providing extended tools for visualisation and validation of models is now available at

(2) The OpenFluor database, for quantitatively comparing NOM-PARAFAC components, will be available as soon as possible at If you have published PARAFAC models that you would like to add to the database at the pre-release stage, please drop me a line. I will email instructions. Models submitted before Nov. 15 will be available for matching as soon as the website goes live. Once the website is live, you can go to and follow the instructions there to upload models directly.

Quantification of natural organic matter

Quantification of natural organic matter: caveats and needs

M. Filella1,2

1 Institute F.-A. Forel, Université de Genève, 10 route de Suisse, CH-1290 Versoix, Switzerland
2 SCHEMA, Rue Principale 92, L-6990 Rameldange, Luxembourg

Natural organic matter (NOM) plays an important role in many environmentally-relevant processes. NOM includes many different types of compounds, not all of which behave similarly. Much effort has gone into characterising some fractions of NOM (e.g., humic substances) in the different environmental compartments, in finding tracers to ascertain their origin, etc. –sometimes by using extremely sophisticated techniques–, but no comparable effort has been put into developing quantification techniques. As a result, field studies have often limited themselves to measuring only total (TOC) or dissolved (DOC) organic carbon or some surrogate parameter.

Quantification of NOM fractions in waters is not straightforward. Any analytical method measures a property of an analyte (or its reaction product) but the operationally defined nature of some NOM categories, together with the concomitant elusive and non-constant composition and structure of some of these substances, makes it difficult to find such an intrinsic property for them. Moreover, results have to be expressed as a function of the response of a standard, which is perceived as unsatisfactory by some users and, more importantly, remains largely misunderstood by many.

Four different cases will be discussed:

  • carbohydrates (or “when not all sugar is glucose”),

  • thiols,

  • TEP (a completely operational category),

  • humics’ (the most difficult case?).

The importance of being able to quantify different types of NOM will be discussed in three different fields: thermodynamic modelling of trace element speciation (and implications for their use in ecotoxicology models such as BLM), understanding the fate of natural colloids and nanoparticles in freshwaters, studying long-term trends of NOM concentrations in relation to global climatic change.